First, you need to Sign-out and close Skype. In this example, we will delete the username playslotsforfreeonline.review from the username choices in the login window or sign- in. I downloaded the Skype app for Windows 8. I have 2 Skype profiles with different username/ password requirements. On the initial sign in to Skype, I logged in Not able to remove Skype account from People App. In this tutorial you will see how to sign out from Skype in Windows 8 / and sign in to another Skype account.